My schedule used to be like this..
Monday - Back and Bi. Most back routines also work the biceps so it made sense. Especially the cable machines, all of them that target back target the bi's too.
Tuesday - Chest and Tri's. Benching, etc.
Wednesday - Shoulders. Shrugs, etc.
Thursday - Legs.
Friday - a little of everything.
cardio every day after working out. i lifted light weights with a lot of reps to try to lose weight and tone up.
my new one is like this..
monday - shoulders. shrugs with 50 lb weights. military press with about 50 [i'm new to military press] the shoulder press machine with 15 on each arm. reverse shrugs with about 80 lbs.
tuesday - chest. benching, i cant bench much. i work out with about 140 now, i know, not a lot. but i use the wide grip while benching, it makes it harder. close grip i can bench a lot more but i feel it works my tri's more than chest so i deem it useless for chest day. then i do the chest press with about a hundred. do butterfly press with 15-20 lb dumbells. pec fly machine with 80 lbs.
wednesday - biceps. curls, etc. everyone knows how to work biceps. i feel they are the strongest part of my upper body, i use heavy weights with my biceps.
thursday - legs. leg press, with about 470 lbs. other leg presses to target other muscles. calf presses with about 300 lbs. squatting, i used to squat a lot of weight but my left knee is really bad so i kinda quit, i do wall squats now, so its my own body weight so its more natural to do.
friday - triceps. all the tricep workouts, skull crushers, etc. my triceps are pretty strong and well defined, so i lift a lot of weight with them too.
saturday - back. i HATE workin out my back. but i do it anyways.. wide grip chin ups. all the aforementioned workouts that use your bi's too. i just hate working out my back..
everyday i do 150 declined sit ups, sometimes i get lazy and do 100. i use the chin up bar to lift the dumbbell to my stomach with my feet, hoping to work my lower abs. every day after working out i play basketball for anywhere from 1-3 hours. even if its just shooting around or a pick up game. after basketball, i swim in the lap pool and use the hot tub to relax my muscles.
sorry for such the long post but you did say you wanted detail...